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Alkalinity Relationships

In water chemistry, the carbon dioxide (CO2=)/carbonic acid (H2CO3), bicarbonate (HCO3-), carbonate (CO3=), and hydroxide (OH-) content affect the pH of the water.  Graphically, the  bicarbonate and carbonate ionic species exist toward the middle of the pH scale between the hydrogen (H+) and hydroxide (OH-) ions as follows: 

Ionic Species

Hydrogen Ion (H+)

 

 

 

 

 

 

 

 

 

 

 

 

Hydroxide Ion (OH-)

100%

 

 

 

 

 

 

 

 

 

 

 

 

 

 

75%

 

 

 

C

 

 

 

 

 

 

C2

 

 

 

50%

 

 

 

 

 

 

 

 

 

 

 

 

 

 

25%

 

 

 

 

 

 

B

 

 

 

 

 

 

 

0%

 

 

 

 

 

 

 

 

 

 

H

 

 

 

 

1

2

3

4

5

6

7

8

9

10

11

12

13

14

<----P Alkalinity to pH 8.3                  

<---M Alkalinity to pH 4.3  

Legend

C

Carbonic Acid 

C2

Carbonate 

B

Bicarbonate

H

Hydroxide

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