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Closed Systems Problems

Black Iron Oxide

Black magnetite sludge forms dense sediments in radiators and the boiler. It clogs pumps and reduces the flow of water through pipes and radiators. An advanced state of corrosion is indicated when black water can be drawn from a radiator air bleed, boiler bleed or a drain cock. Black oxide is formed in all untreated heating system.

Red Iron Oxide

Red or brown rust is only formed in heating systems when systems are aerating. Aeration faults must be cured when replacing failed components to prevent further failures.

Hydrogen Gas (Highly flammable)

Hydrogen is a by-product of corrosion processes and may necessitate frequent venting. Hydrogen is often mistaken for air. It can be detected by igniting it at a radiator vent and it burns with a yellow flame. Gas accumulations depress the water level, disturbing the flow pattern in the radiators thus causing cold radiators.

Galvanic Effects

Galvanic corrosion is a well known and contributes significantly to the deterioration of central heating systems. In the presence of the copper, steel & aluminum become "sacrificial", just as in a consumable battery.

Some of the ways in which galvanic corrosion occurs are:

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Copper pipe in electrical contact with radiator.

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Brass fittings

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Pieces of copper in radiators.

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Sediments of ferrous oxide (magnetite).

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Folds in steel radiators - stressed areas sacrificial.

Impurities

Impurities in the water can play a very big part in central heating corrosion processes. Corrosion rates are increased by soldering fluxes containing chlorides. New systems should be pre-commission cleansed in accordance with BS7593 to avoid such problems 

Pinhole or Perforated Radiators

These have occurred due to localized pitting as a result of a combination of the above circumstances.

Boiler Noises

Localized boiling can develop where there is sludge or scale in the heat exchanger causing very high internal skin temperatures which results in steam bubbles forming in the heat exchanger.

Air in Central Heating Systems

Air circulating in the water not only gives rise to rapid corrosion, but associated noise and the necessity for frequent venting represent a nuisance. Aeration indicates the presence of a FAULT.

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