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Organic
Water Treatment Chemicals
Steam Boilers, Cooling Towers,
Hot And Chilled Closed Systems
Fuel Oil Treatment
(Home of D.M Concentrate)
HARD
WATER
How
it Affects Our Daily Lives
Simply stated, water hardness
refers to the amount of calcium,
magnesium, carbonate, and
sulfate dissolved in the water
entering your home or business.
When hardened water becomes over
saturated with minerals, is
heated, or is placed under the
increasing pressure of smaller
water pipes, the dissolved
minerals come out of solution
(precipitate) and attach to our
plumbing and hot water
appliances. Hard water minerals
can precipitate out of solution
anywhere in our plumbing system.
However, the heating of hard
water is responsible for most of
the damage caused to hot water
heaters and other appliances as
well as the unsightly scale we
observe on faucet screens and
shower heads.
Water hardness depends on your
location and water source.
Typically, water from
underground sources such as
wells and acquafers is harder.
To determine how hard your water
is, call your local water
company and ask for the water
hardness in grains per gallon (gpg)
or milligrams per liter (parts
per million/ppm). As an
alternative, order a free water
test simply by mailing me a
request. Use the following chart
to determine the extent of your
hard water problem:
|
Term
|
Grains/Gallon
(gpg)
|
Mg/Liter
(ppm)
|
|
Soft
|
Less
than 1.0
|
Less
than 17.1
|
|
Slightly
Hard
|
1.0
to 3.5
|
17.1
to 60
|
|
Moderately
Hard
|
3.5
to 7.0
|
60
to 120
|
|
Hard
|
7.0
to 10.5
|
120
to 180
|
|
Very
Hard
|
10.5
and Above
|
180
and Above
|
How
Water Gets Hard
The best way to explain how
water gets hard (ladened with
potential damaging minerals) is
to start with rain water which
is naturally soft, having less
than 1 grain per gallon (gpg) of
dissolved mineral. Rain water is
called a "universal"
solvent because of its natural
ability to clean. Water forms
when
water vapor
in the air interacts with
particulate mater to form
raindrops. As rain falls, it
absorbs other materials, some of
which cause the water to form a
slightly acidic pH. This primes
the water droplet with an extra
measure of solvency. The
solvency characteristics of rain
water are further enhanced when
the rain water interacts with
polluted air and, while on the
ground, flows through
environments which further
acidify it. When water flows
through and over areas
consisting chiefly of calcareous
and other limestone based rocks,
these calcium and magnesium
carbonate surfaces, which
normally would not dissolve in
water, are affected by the
acidic water which turns
carbonates (insoluble) into
bicarbonates (soluble). Thus,
surface salts which normally
would not find their way into
our water, are trapped and
carried as unwilling passengers
in the form of calcium (+) and
carbonate (-) ions. The minerals
are surrounded by water
molecules and carried as
complexes within the water.
As the water continues to flow
to its final resting point, it
dissolves additional minerals
but at a decreasing rate. This
is because the dissolved
minerals cause the surface
tension of the water to increase
thus decreasing the water's
ability to dissolve additional
material. The hardness of water
flowing into your house or
business depends on the extent
of its exposure to surface and
sub-surface rocks and limestone
structures and the extent to
which it was subjected to acidic
influences. The hardest water
comes from wells and aquifers.
However, some wells are
exceedingly soft while some
public water supplies are
exceedingly hard. About 3/4ths
of the country is plagued with
problematic water hardness.
Why
Dissolved Minerals Solidify in
Our Plumbing and Appliances
Dissolved minerals, primarily
bicarbonates of calcium and
magnesium, remain within their
host complexes under normal
conditions. As a result, the
dissolved particles, devoid of
any nucleation centers for
growth and escape from the
water, flow evenly within the
water having no particular
tendency to bind together or
lose their solubility. However,
when the mineral content of the
water becomes over saturated, is
heated, or placed under
pressure, the complexes become
agitated, break up and the (+)
and (-) ions lose their polarity
allowing the minerals to clump
into larger masses. The clumping
effect makes it more difficult
for the minerals to remain
soluble and the crystallized
mineral precipitates out of
solution. Two types of
crystallization occur.
The first, which occurs in the
hottest part of the heat
exchanger (hot water heater
heating element, for example),
results in a mineral form called
calcite. Calcite is an
adherent mineral that attaches
itself to the surface of the
heat exchanger. Repeated
collisions cause the build up of
more and more scale on the heat
exchange surface. Since mineral
scale is an insulator, transfer
of heat from the heating element
to the water is gradually
reduced causing more energy to
be consumed to heat the same
water. This is why scale
build-up on your water heater's
heating element can increase
your energy bill by 10% to
40%..or more!
The second type of
crystallization occurs when
carbonate forms in a lower heat
environment away from a heat
exchanger. The resulting mineral
formation is called aragonite.
While aragonite can still adhere
to surfaces (faucet screens and
shower heads for example) its
primary form is non adherent and
tends to form smaller grained or
softer scale deposits. These
deposits remain stable upon
heating and can be carried
throughout the heating or
cooling system causing little or
no damage. This type of scale is
what collects at the bottom of
your water heater, becomes
trapped in faucet mounted
filters, appears as toilet bowel
discoloration (1), or moves through and out of your home through the
water pipes.
Why We Should Be Concerned About Hard Water
Hard
water leads to higher energy
costs to heat water. The
US Department of Energy (DOE)
reports that as little as a 1/32
inch scale build-up on a heat
exchange surface (hot water
heater, boiler, cooling tower,
etc.) causes you to use almost
10% more energy. A 1/4 inch
build-up will increase energy
consumption by a whopping 40%!
This can cost hundreds or even
thousands of wasted energy
dollars per year for home or
business.
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